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61.
62.
《International Journal of Hydrogen Energy》2021,46(63):31952-31962
Vanadium redox flow battery (VRFB) is the best choice for large-scale stationary energy storage, but its low energy density affects its overall performance and restricts its development. In order to improve the performance of VRFB, a new type of spiral flow field is proposed, and a multi-physics coupling model and performance metrics evaluation system are established to explore the electrolyte distribution characteristics. The results show that the new spiral flow field can effectively improve the uniformity of electrolyte flow and alleviate the phenomenon of local concentration polarization as compared with the traditional serpentine flow field and parallel flow field. Due to the long flow channel and large pressure drop, the system efficiency is low. However, coulombic efficiency, voltage efficiency and energy efficiency are significantly better than the traditional flow fields. Therefore, the novel flow field has obvious advantages in the application of small stacks. 相似文献
63.
Compared with other ways to produce hydrogen, water electrolysis is the best way to obtain ultra-pure hydrogen, but its low energy efficiency greatly limits its wide application. It was proved that external magnetic field can reduce energy consumption, thereby increase electrolysis efficiency. Most of the researchers are focused on the impact of uniform magnetic field but few on a non-uniform one. To address the industrial operation reality, in our work, water electrolysis was operated using alkaline solution and plate electrodes in a non-uniform Magnetic field. The results show that a rotational flow on the vertical plane was formed by Lorentz force within the entire cell range. Although the entrainment effect of rotating flow made the cell full of microbubbles, the cell voltage was still reduced. By measuring the voltage difference of cathode side and anode side, we think that the bubble layer in the vicinity of the electrode surface matters the most among the sources of electric resistance. And the velocity distribution near the electrode was measured by PIV, it reveals that MHD flow is the dominant effect on the flow field of the cell. The results show that non-uniform magnetic field has potential merit in industrial electrolysis process. 相似文献
64.
Kush Chadha Serguei Martemianov Anthony Thomas 《International Journal of Hydrogen Energy》2021,46(10):7489-7501
Efficiency of fuel cell is dependent on reactant distribution, products evacuation, pressure losses and many of these factors is dependent on the design of flow field plate. With an effective design, reactant distribution, pressure drop, and water and heat management can be further improved. In this work, two new designs, as multi-serpentine set-up with additional slots and hybrid geometry, on stainless steel bipolar plates, are presented. Electrical performance, and pressure head losses are analyzed by electrochemical methods such as polarization curve and use of electrochemical noise as a diagnostic tool to further understand the impact of water management on performance. On the one hand, multi-serpentine design shows the best electrical performance with an increase of 0.2 V (66%) at 0.9 A/cm2 in comparison of traditional serpentine design. On the other hand, hybrid design reveals the lowest pressure head losses, with a decrease of 2 mbar (about 50%) in comparison of traditional serpentine design, and a higher stability with time that can be useful to downsize compressor and provide lower impact on fuel cell stack durability. 相似文献
65.
66.
《Oil and Energy Trends》2019,44(5):23-27
Current data on crude oil, field/lease condensate, and natural gas liquids produced from NGL plants. Updated on a monthly basis. 相似文献
67.
为了综合利用氧化铝冶炼产生的赤泥,探索在转底炉中直接还原赤泥、磨矿磁选获得高品位直接还原铁。通过实验室试验摸索了转底炉还原工艺参数,并在转底炉工业试验线进行了工业试验。实验室结果表明,赤泥还原后的直接还原铁(DRI)金属化率可达88.6%,磁选后的铁品位可达82.1%,磁选后的铁回收率可达88.9%。工业试验中,转底炉还原后,产品金属化率平均为69.2%,将还原后的DRI磁选获得高品位的DRI产品,磁选后DRI的铁品位为72.8%,磁选后铁回收率达到了85.2%,初步打通了在转底炉中还原赤泥、磁选的工艺路径。 相似文献
68.
铝电解车间具有高温、强磁、多粉尘等环境特点,当前生产过程中熔融原铝的成分检测主要是人工取样然后离线分析,化验过程及结果具有较大的滞后性,故将激光诱导击穿光谱(LIBS)技术应用于铝电解车间铝液成分原位、实时测量具有重要意义。实验采用Nd:YAG脉冲激光器,多通道光纤光谱仪和电感耦合器件(CCD)探测器组成的激光诱导击穿光谱测量系统对电流为400kA电解槽中熔融铝液的主要成分铁、硅进行了探测,对原铝中部分元素的特征谱线进行了归属分析。考察了激光能量在磁场环境下的衰减变化及谱线梯度变迁规律,结果表明,距离电解槽边缘约2m处激光能量衰减达最大。分析了磁场对测试系统的影响,并建立了定标曲线,铁和硅两种元素按照内标法建立的定标曲线拟合度分别为93.50%和97.10%,采用该模型进行了测试实验,并用国标GB/T 7999—2015中光电直读发射光谱(OES)测试的相关指标验证测试结果的重复性与允许差。实验证明,LIBS技术在电解铝行业在线检测方面具有较好的应用前景,但是测试的稳定性与重复性也是面临的一个重要问题。 相似文献
69.
使用基于克里金理论的插值计算方法对均匀网格与随机排列等不同分布类型的辐射剂量场进行了数据重构与可视化研究,并将重构结果与常用的反距离加权插值法进行了对比,分析了不同插值方法对辐射剂量场重构精度与可视化显示效果的影响。结果表明:对于多数情况,克里金插值法在辐射剂量场重构的精度与可视化显示的效果上均明显优于反距离加权插值法,算例中克里金插值法的结果与原始数据之间的偏差在10%以内,而反距离加权插值法的结果与原始数据之间的偏差基本在15%以上;但在辐射剂量场梯度变化较大且已知数据极少的区域,克里金插值法的计算结果偏差会增大,此时可使用反距离加权插值作为其补充,综合使用。本文的研究工作,验证了克里金插值法在辐射剂量场重构与可视化方面的应用潜力,可为推动辐射剂量场可视化仿真技术的发展提供技术支持。 相似文献
70.
The enhanced photocatalytic activity of Na0.9Mg0.45Ti3.55O8 co‐loaded with silver and platinum 下载免费PDF全文
Jing‐Zhou Wang Ze‐Qing Guo Jian‐Ping Zhou Yu‐Xi Lei Xuan‐Xuan Shi Qadeer Ul Hassan 《国际能源研究杂志》2018,42(3):1056-1065
Noble metals Ag and Pt were loaded on Na0.9Mg0.45Ti3.55O8 (NMTO) by chemical bath deposition method, which was synthesized firstly in our recent work. The scanning electron microscopy and transmission electron microscopy results show that Ag and Pt nanoparticles were distributed on the different surfaces of NMTO. NMTO loaded with Ag and Pt can efficiently enhance the separation of photogenerated electron‐hole pairs, exhibiting much higher photodegradative ability for methylene blue and rhodamine B than the pure NMTO. The best weight concentrations of Ag and Pt are 9.00% and 3.70%, respectively. The electrostatic field is built in the Schottky barrier between NMTO and noble metals, leading to the energy band bending. Then, photogenerated electrons and holes are efficiently separated to enhance the photocatalytic activity. 相似文献